吴坤,周贻兵,李存雄

• 1:贵州师范学院化学与生命科学学院
• 2:贵州省疾病预防控制中心

摘要(Abstract)：

离子液体具有结构可设计性、难挥发、可循环使用等优点,在有机反应中得到了广泛的应用。综述了离子液体的物理化学性质对有机反应体系中底物、催化剂、溶剂的作用及可能的机理。

关键词(KeyWords)： 离子液体;有机反应;作用机理

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 吴坤,周贻兵,李存雄

DOI: 10.13391/j.cnki.issn.1674-7798.2013.06.007

参考文献(References)：

• [1]PENG J,DENG Y.Catalytic Beckmann rearrangement ofcyclohex-anone oxime in ionic liquids[J].TetrahedronLett,2001,42:403-406.
• [2]REN R X,OU W.Preparation of cyclic ketoximes usingaqueous hydroxyl amine in ionic liquids[J].TetrahedronLett,2001,42:8445-8446.
• [3]Zhang Z F,Xie Y,Li W J,et al.Hydrogenation of car-bon dioxide is promoted by a task-specific ionic liquid[J].Angew Chem Int Ed,2008,47:1127-1129.
• [4]T.P.Wells,J.P.Hallett,C.K.Williams,et al.Ester-ification in Ionic Liquids:The Influence of Solvent Basic-ity[J].J.Org.Chem,2008,73:5585-5588.
• [5]J.-C.Hsu,Y.-H.Yen,Y.-H.Chu.Baylis–Hillman reaction in[bdmim][PF6]ionic liquid[J].Tetrahedron Lett,2004,45:4673-4676.
• [6]王波,杨立明,索继栓.温和条件下离子液体/水两相体系中α,β-不饱和羰基化合物的环氧化反应研究[J].化学学报,2003,61:285-290.
• [7]A.Aggarwal,N.L.Lancaster,A.R.Sethi,et al.Therole of hydrogen bonding in controlling the selectivity ofDiels–Alder reactions in room-temperature ionic liq-uids[J].Green Chem,2002,4:517-520.
• [8]T.Gutel,P.Campbell,C.C.Santini,et al.On the in-fluence of ionicity over catalysis in ionic liquids[J].Chim.Oggi Chem.Today,2009,27:48-50.
• [9]J.Mo,L.J.Xu,J.L.Xiao.Ionic Liquid-Promoted,Highly Regioselective Heck Arylation of Electron-RichOlefins by Aryl Halides[J].J.Am.Chem.Soc.,2005,127:751-760.
• [10]Wang,R.H.,Twamley,B.,Shreeve,J.M.A High-ly Efficient,Recyclable Catalyst for CC Coupling Re-actions in Ionic Liquids:Pyrazolyl-Functionalized N-Heterocyclic Carbene Complex of Palladium(II)[J].J.Org.Chem.,2006,71:426-429.
• [11]江洋洋,刘会洲,郭晨,等.固定化离子液体在催化与分离方面的应用进展[J].过程工程学报,2007,01:194-201.
• [12]Legeay,J.-C.,Eynde,J.J.V.,Bazureau,J.P.Ionicliquid phase technology supported the three componentsynthesis of Hantzsch 1,4-dihydropyridines and Bigi-nelli 3,4-dihydropyrimidin-2(1H)-ones under mi-crowave dielectric heating[J].Tetrahedron,2005,61:12386-12397.
• [13]Peng,Y.Q.,Yi,F.P.,Song,G.H.,et al.SolutionPhase Parallel Synthesis of 4-Aminophenyl Ethers U-sing a Carboxyl-Functionalized Ionic Liquid as Support[J].Monatsh.Chem.,2005,136:1751-1755.
• [14]Miao,W.,Chan,T.H.Exploration of Ionic Liquids asSoluble Supports for Organic Synthesis Demonstrationwith a Suzuki Coupling Reaction[J].Org.Lett,2003,5:5003-5005.
• [15]Handy,S.C.,Okello,M.Fructose-derived ionic liq-uids:recyclable homogeneous supports[J].TetrahedronLett.,2003,44:8399-8402.
• [16]Legeay,J.C.,Jougon,J.Y.Eynde,J.J.V.,et l.Liquid-Phase Synthesis of Polyhydroquinoline Using Task-Specific Ionic Liquid[J].Technology Comb.Chem,2006,8:829-833.
• [17]Zhichang Liu,Rui Zhang,Chunming Xu,etal.Ionicliquid alkylation process produces high-quality gaso-line[J].Oil&Gas Journal,2006,104(40):52-56.
• [18]Y.Liu,R.Hu,C.Xu,et al.Alkylation of isobutenewith 2-butene using composite ionic liquid catalysts[J].Appl.Catal.A,2008,346:189-193.
• [19]F.Bessac,F.Maseras,DFT modeling of reactivity inan ionic liquid:How many ion pairs[J].J.Comput.Sci.2008,29:892-899.
• [20]B.Gilbert,H.Olivier-Bourbigou,F.Favre.Chloro-aluminate Ionic Liquids:from their Structural Propertiesto their Applications in Process Intensification[J].OilGas Sci.Technol,2007,62:745-760.
• [21]H.S.Schrekker,M.A.Gelesky,Marcelo P.Stracke,etal.Disclosure of the imidazolium cation coordination andstabilization mode in ionic liquid stabilized gold(0)nanop-articles[J].J.Colloid Interface Sci,2007,316:189-195.